10 questions🇬🇧English

🧪 Alkenes & Electrophilic Addition – A-level

Chemistry · A-level — practises E/Z isomerism, addition mechanisms, carbocation stability and polymers

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Questions

Which description correctly matches the bonding in a C=C double bond?

One σ bond and one π bond
Two σ bonds
One σ bond and two π bonds
Two π bonds
20s

Bromine water is shaken with an alkene. What colour change is seen?

Colourless to orange
Orange to colourless
Purple to colourless
Orange to green
20s

Which of these alkenes shows E/Z isomerism?

But-1-ene
Propene
But-2-ene
2-methylpropene
20s

Which is the repeat unit of poly(propene)?

–CH₂–CH₂–
–CH₂–CH(CH₃)–
–CH₂–CH₂–CH₂–
–CH₂–C(CH₃)₂–
30s

What is the major product when propene reacts with hydrogen bromide?

Propan-2-ol
2-bromopropane
1,2-dibromopropane
1-bromopropane
30s

In the mechanism of ethene with HBr, the first curly arrow starts at the C=C bond. Where does it point?

To a carbon atom in the alkene
To the H atom of HBr
To a lone pair on Br
To the Br atom of HBr
30s

Why is a tertiary carbocation more stable than a primary carbocation?

More alkyl groups push electron density onto C⁺
The tertiary C⁺ has a full outer shell
Alkyl groups withdraw electrons from C⁺
Fewer alkyl groups crowd the C⁺
30s

Br₂ is a non-polar molecule. How can it act as an electrophile towards an alkene?

The C=C electron density induces a dipole in Br₂
Br₂ is permanently polar like HBr
Br₂ splits into Br radicals in the dark
The alkene donates a proton to Br₂
30s

Propene reacts with cold concentrated H₂SO₄ and the product is then warmed with water. What is the major organic product?

Propyl hydrogensulfate
Propan-2-ol
Propane-1,2-diol
Propan-1-ol
30s

In one isomer of 2-chlorobut-2-ene, CH₃C(Cl)=CHCH₃, both CH₃ groups are on the same side of the C=C. What is it?

The Z isomer
The E isomer
It has no E/Z isomers
A racemic mixture
60s